Rhodium and Iridium Hydroxide Complexes [M(μ-OH)(COD)]
<sub/>2</sub>
(M = Rh, Ir) as Versatile Precursors of Homo and Early−Late Heterobimetallic Compounds. X-ray Crystal Structures of Cp*Ta(μ
<sub/>3</sub>
-O)
<sub/>4</sub>
[Rh(COD)]
<sub/>4</sub>
(Cp* = η
<sup>5</sup>
-C
<sub/>5</sub>
Me
<sub/>5</sub>
) and [Ir(2-O-3-CN-4,6-Me
<sub/>2</sub>
-C
<sub/>5</sub>
HN)(COD)]
<sub/>2</sub>

Rhodium and Iridium Hydroxide Complexes [M(μ-OH)(COD)] ₂ (M = Rh, Ir) as Versatile Precursors of Homo and Early−Late Heterobimetallic Compounds. X-ray Crystal Structures of CpTa(μ ₃ -O) ₄ [Rh(COD)] ₄ (Cp = η ⁵ -C ₅ Me ₅ ) and [Ir(2-O-3-CN-4,6-Me ₂ -C ₅ HN)(COD)] ₂

Fandos, Rosa; Hernández, Carolina; Otero, Antonio; Rodríguez, Ana; Ruiz, Maria José; García Fierro, José Luis; Terreros, Pilar