Thermal hysteresis in dithiadiazolyl and dithiazolyl radicals induced by supercooling of paramagnetic liquids close to room temperature: a study of F3CC???NSSN??? and an interpretation of the behaviour of F3CC???SNSC???CF3Electronic supplementary information (ESI) available: Synthesis of 1; packing diagrams of 1 and 2; ab initio calculations on the association modes of 1 and 2; estimates of the energy of association of 2 based on a simple electrostatic model; molecular electrostatic potential maps of 1 and 2 and a comparison of the charge distribution in 1 and 2 from semi-empirical and ab initio calculations; curve-fits of the magnetic data of 1 utilising a Curie???Weiss, exchange-coupled dimer and monomer???dimer equilibrium models for the liquid phase. See http://www.rsc.org/suppdata/cc/b2/b202627a/
- 期刊名称Chemical Communications
- 作者Du, Hongbin; Haddon, Robert C.; Krossing, Ingo; Passmore, Jack; Rawson, Jeremy M.; Schriver, Melbourne J.
- 期第17期
- 印刷ISSN1359-7345
- 电子ISSN1364-548X
- 文件大小116.48KB
- 发表时间2002-8-21
- DOI10.1039/b202627a
- 页码1836-1837
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